许环军

一、基本情况

许环军，男，博士（博士后），湖南郴州人，目前挂职琼台师范学院理学院副院长，海南省化工协会理事。

2019.03-至今 琼台师范学院理学院 化学专任教师

2019.11-2021.10 海南大学生物学博士后流动站  

2018.11-2019.03 山东省科学院新材料研究所 助理研究员

2015.07-2018.11 海南碧凯药物研究所有限公司 新药研究室主任

2012.09-2015.07 中国科学院化学研究所 物理化学 博士  

2009.09- 2012.07 沈阳药科大学中药学院 天然药物化学 硕士  

2005.09 - 2009.07 哈尔滨商业大学药学院 制药工程/医药商务(第二学位)

二、教学方面

主讲课程：有机化学、基础化学、化学与生活。

三、科研方面

研究方向：绿色有机化学、绿色新材料的合成及应用、废弃生物质的绿色催化转化。

目前主持厅级以上项目6项，其中国家自然科学基金地区项目1项，海南省自然科学基金高层次人才项目1项、青年项目1项，海南省高等学校科学研究重点项目1项，海南省博士后科研资助1项、面上资助1项。带领团队教师获批海南省自然科学基金3项，海南省高等学校科学研究项目3项，海南省规划课题1项。已发表论文38篇，其中SCI论文29篇，申请发明专利1项。带领学生获批创新创业项目国家级3项，省级3项，此外作为指导老师带领团队学生获得2022年度中美创客海口赛区二等奖1项，2021年度海南青少年和安全知识竞赛三等奖1项，入选2021年“强国有我‘核’你一起”千支大学生志愿宣讲团入选名单，团队学生以一作身份发表论文6篇，其中SCI 4篇。

科研项目：

国家自然科学基金地区项目，新型全共轭高晶态石墨炔材料的构筑及其本征性能探索（22165009），35万，2022-01-01到2025-12-31，主持；

海南省自然科学基金高层次人才项目，基于超临界二氧化碳还原断裂木质素及木质素模型化合物芳香C-O键制备芳烃研究（2019RC250），10万，2020-01-01到2022-12-31，主持；

海南省自然科学基金青年项目，基于富炔型COFs负载超细金属纳米颗粒及其催化性能（220QN281），5万，2020-12-26到2023-12-25，主持；

海南省高等学校科学研究重点项目，基于氢溢流富炔COFs储氢材料的设计与合成（Hnky2021ZD-22），3万，2021-01-01到2023-12-31，主持；

海南省人才局，海南省博士后科研资助，基于富炔型COFs负载超细金属纳米颗粒及其催化性能，8万，2020-11-01至2021-10-31，主持；

海南省人才局，海南省博士后面上资助，基于富炔型COFs负载超细金属纳米颗粒及其催化性能，5万，2020-11-01至2021-10-31，主持；

琼台师范学院，校级一般项目，负氢试剂/强碱催化还原断裂木质素C-O键制芳烃机理研究（qtyb201908），1万，2020-11-01至2021-10-31，主持；

琼台师范学院科研启动金，10万，主持；

指导学生国家级创新创业项目3项，省级3项；

海南省重大科技专项子课题，深海自主无人车系统及其高时效精细化立体观测技术研究（ZDKJ202016），80万，2020-12-11至2023-12-11，参与.

论文和专利情况：

[1] Xiaodan Wang^‡, Huilin Sun^‡,Yao Cheng^‡,Wenfei Yang,Xinmei Wang,Liting Xiong,Yiying Li,Jinhui Wang,Chunli Gan*,Chunguang Lin*, Huanjun Xu*. Ethyl acetate as an acetyl source and solvent for acetylation of alcohols by KOH. RSC Advances, 2024, 14, 12574-12579.

[2] Chi Li^‡, Yu Gao^‡, Han Li^‡, Wenhao Li, Xinmei Wang, Xuerong Wang, Chunguang Lin, Jinhui Wang*, Yiying Li*, Huanjun Xu*. Metal catalyst-free oxidative cleavage of aryl C(OH)-C bonds. ChemistrySelect, 2023, 34, e202301252.

[3] Xue Wang^‡,Xinyuan Guo^‡, Xinmei Wang^‡,Chi Li,Shanjun Wang,Han Li,Yan'an Gao,Yiying Li,*Jinhui Wang,*Huanjun Xu*. Conversion of 5-hydroxymethylfurfural to furan-2,5-dicarboxylic acid by a simple and metal-free catalytic system. RSC Advances, 2023, 13, 13819-13823.

[4] Xuerong Wang,^# Yu Gao^#, Ying Chen^#, Huilin Sun, Caicui Li, Chaohai Pang, Yanan Gao, Xiaolin Zhang,* Ruijing Cheng*, Huanjun Xu*, Jinhui Wang. Transition metal-free aerobic oxidation of aryl secondary and primary alcohols to carbonyl compounds in open air. ChemistrySelect, 2022, 21, e202103502.

[5] Xinwei Liu*, Liguo Wang, Lianjing Zhai, Cailing Wu*, Huanjun Xu*. H₂O₂ promoted C-C bond oxidative cleavage of β-O-4 lignin models to benzanilides using water as solvent under metal-free conditions. Green Chemistry, 2022, 24, 4395-4398.

[6] Xuerong Wang^†, Huilin Sun^†, Caicui Li^†, Shuijiao Niu, Yu Gao,Ying Chen, Tianwei Xu*, Jinhui Wang*, Huanjun Xu*. Catalytic oxidative cleavage of C(OH)-C bonds in lignin model compounds to carboxylic acids by Fe(NO₃)₃.9H₂O/NaI/DMSO. Frontiers in Chemistry, 2022, 10, 933763.

[7] Xuerong Wang^#, Chi Li^#, Xinyuan Guo^#, Zhichao Wang, Ruijing Cheng, Tianwei Xu, YiYing Li*, Jinhui Wang*, Huanjun Xu*. Preparation of Pd nanoparticles stabilized by modified montmorillonite for efficient hydrodeoxygenation of lignin-derived phenolic compounds in water. Frontiers in Chemistry, 2022, 10, 961814.

[8] Yuying Chai^#, Yaling Li^#, Hui Hu, Chaoyuan Zeng*, Shenglin Wang, Huanjun Xu*, Yanan Gao*. N-Heterocyclic carbene functionalized covalent organic framework for transesterification of glycerol with dialkyl carbonates. Catalysts, 2021, 11, 423.

[9] Qianqian Yan^#, Huanjun Xu^#, Xuechao Jing, Hui Hu, Shenglin Wang, Chaoyuan Zeng*, Yanan Gao*. Post-synthetic modification of imine linkages of a covalent organic framework for its catalysis application. RSC Advances, 2020, 10, 17396-17403.

[10] Huanjun Xu, Xinwei Liu, Yanfei Zhao, Cailing Wu, Yu Chen, Xiang Gao, Zhimin Liu*.Reductive cleavage of C-O bond in model compounds of lignin. Chinese Journal of Chemistry, 2017, 35(6): 938-942.

[11] Huanjun Xu, Bo Yu, Hongye Zhang, Yanfei Zhao, Zhenzhen Yang, Jilei Xu, Buxing Han, Zhimin Liu*. Reductive cleavage of inert aryl C-O bonds to arenes. Chemical Communications, 2015, 51(61): 12212-12215.

[12] Huanjun Xu, Kongchen Wang, Hongye Zhang, Leiduan Hao, Jilei Xu, Zhimin Liu*.Ionic liquid modified montmorillonite-supported Ru nanoparticles: highly efficient heterogeneous catalysts for the hydrodeoxygenation of phenolic compounds to cycloalkanes. Catalysis Science & Technology, 2014, 4(8), 2658-2663.

[13] 许环军, 康帅涛, 李晓东,战德胜,黄健, 王金辉*. 苄基保护的α-D-葡萄糖三氯乙酰亚胺酯的合成工艺及分离方法的改进. 沈阳药科大学学报, 2012, 5, 352-354.

[14] 许环军, 程睿菁, 张晓琳,刘斌, 李祎莹*. 基于氢化断裂木质素及其模型化合物C-O键的研究进展. 云南化工, 2019, 4, 10-12.

[15] 许环军, 程睿菁, 李祎莹.绿色化学理念在科学教育中的贯穿--以琼台师范学院为例. 年轻人, 2019, 47, 67-67.

[16] 许环军, 代书杰, 庞蕊弦, 程睿菁. 琼台师范学院理学院科学教育专业“专升本”教学方法改革初探. 智库时代, 2020, 45, 141.

[17] 许环军, 李祎莹. 丹酚酸 A 及其类似物的合成研究进展, 医药卫生, 2021, 2, 0032-0034.

[18] 高宇, 孙慧琳, 李驰, 郭鑫源, 许环军*. 共价有机框架材料在生物领域的应用研究. 进展:科学视界, 2022, 1, 65-66.

[19] 闫羿辰, 黄铭娇, 李彩翠,陈颖, 许环军*. 稳定型共价有机框架材料的研究进展. 进展:科学视界, 2021, 12, 128-129.

[20] Shenglin Wang⁺, Qianqian Yan⁺, Hui Hu*, Xiaofang Su, Huanjun Xu, Jianyi Wang, Yanan Gao*. Doping ferrocene-based conjugated microporous polymers with 7,7,8,8-tetracyanoquinodimethane for efficient photocatalytic CO₂ reduction. Molecules, 2024, 29(8), 1738.

[21] Wenyu Zhong, Ming Wang, Hui Hu, Jiaying Qian, Shenglin Wang, Xiaofang Su*, Songtao Xiao*, Huanjun Xu, Yanan Gao*. Ultrahigh-efficient N,O-functionalized covalent organic framework towards thorium adsorption from uranium and rare earth elements. Separation and Purification Technology, 2024, 347, 127603.

[22] Weitao Wang*, Haishun Guo, Yuan Zhang, Huan Wang, Xiufang Yang, Huanjun Xu, Lu Li and Yangmin Ma. Sulfonic acid-functionalized molecular sieve as a solid acid catalyst for transformation of agricultural residues to furfural. ACS Agric. Sci. Technol. 2023, 3(9), 822-834.

[23] Siyu Luo, Qianqian Yan, Shenglin Wang, Hui Hu*, Songtao Xiao*, Xiaofang Su, Huanjun Xu, Yanan Gao*. Conjugated microporous polymers based on octet and tetratopic linkers for efficient iodine capture. ACS Applied Materials & Interfaces, 2023, 15, 46408-46416.

[24] Xia Zhang, Shenglin Wang, Kun Tang, Wei Pan, Huanjun Xu, Yanhua Li*, Yanan Gao*, Na Li*, Bo Tang*. Cu²⁺ embedded three-dimensional covalent organic framework for multiple ROS-based cancer immunotherapy. ACS Applied Materials & Interfaces, 2022, 14(27), 30618-30625.

[25] Peng Tian, Zhiting Ai, Hui Hu,Ming Wang, Yalin Li, Xinpei Gao, Jiayin Qian, Xiaofang Su*, Songtao Xiao*, Huanjun Xu, Fei Lu, Yanan Gao*. Synthesis of electron-rich porous organic polymers via schiff-base chemistry for efficient iodine capture. Molecules, 2022, 27(16), 5161.

[26] Yan Qianqian, Liang Hao, Wang Shenglin, Hu Hui, Xiaofang Su*, Songtao Xiao*,Huanjun Xu, Xuechao Jing, Yanan Gao*. Immobilization of ionic liquid on a covalent organic framework for effectively catalyzing cycloaddition of CO₂ to epoxides. Molecules, 2022, 27(19), 6204.

[27] Muyun Huang, Lu Li, Zhiting Ai, Xinpei Gao, Jiaying Qian, Huanjun Xu, Xiaofang Su, Jifeng Wu*, Yanan Gao*. One-step fabrication of ice-templated pure polypyrrole nanoparticle hydrogels for high-rate supercapacitors. ACS Applied Nano Materials, 2022, 5(8), 11940-11947.

[28] Yaling Li^‡,Kaiming Zuo^‡,Tingjun Gao,Jifeng Wu,Xiaofang Su,Chaoyuan Zeng*,Huanjun Xu,Hui Hu,Xiaosong Zhang, Yanan Gao*. Bimetallic docked covalent organic frameworks with high catalytic performance towards coupling/oxidation cascade reactions. RSC Advances, 2022, 12, 4874-4882.

[29] Zhongliang Wen, Shenglin Wang, Siyao Fu, Jiaying Qian, Qianqian Yan, Huanjun Xu, Kaiming Zuo, Xiaofang Su*, Chaoyuan Zeng*, Yanan Gao*. A two-dimensional dual-pore covalent organic framework for efficient iodine capture. Chemical Research in Chinese Universities, 2022, 38, 472-477.

[30] Baobao Zeng^#, Jianwei Liang^#, Chong Fu, Zhenqiang Zhang, Huanjun Xu, Danfeng Yu*, Xudong Luo, Wei Liu*, Xin Deng, Gao Yang*, Guangzhou Xu. Synergistic effect of nano-silica and eco-friendly hydrogel for the cost-effective and highly efficient oil-water separation. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 636, 128136.

[31] Yaling Li, Jianqiang Zhang, Kaiming Zuo, Zhongping Li, Yu Wang, Hui Hu, Chaoyuan Zeng*, Huanjun Xu, Baoshan Wang*, Yanan Gao*. Covalent organic frameworks for simultaneous CO₂ capture and selective catalytic transformation. Catalysts, 2021, 11, 1133.

[32] Tingjun Gao, Xiaofang Su, Huanjun Xu, Hui Hu, Chaoyuan Zeng*, Yanan Gao*. Construction of the copper‐functionalized covalent organic framework used as a heterogeneous catalyst for click reaction. ChemistrySelect, 2020, 5, 15010-15014.

[33] Vasanthakumar Arumugam, Ramar Rajamanikandan, Malaichamy Ilanchelian, Huanjun Xu, Kandasamy G. Moodley*, Yanan Gao*. Spectroscopic and thermodynamic studies on binding behaviour of an ionic liquid, 2′,3′-Epoxypropyl-N-methyl-2-oxopyrrolidinium acetate, with bovine serum albumin (BSA). Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020, 601, 124954.

[34] Kandsamy G Moodley^#, Vasanthakumar Arumugam^#, Oriyomi P Ogundele, Huanjun Xu, Gan G. Redhi*, Yanan Gao*. Thermophysical and thermodynamic properties of binary liquid systems of [BMIM][MeSO₄] ionic liquid with carboxylic acids. Indian Journal of Chemistry, Section A, 2020, 59, 1136-1147.

[35] Keyu Geng, Vasanthakumar Arumugam, Huanjun Xu, Yanan Gao*, Donglin Jiang*.Covalent organic frameworks: Polymer chemistry and functional design. Progress in Polymer Science, 2020, 108, 101288.

[36] Ming Wang, Hua Hou, Baoshan Wang, Huanjun Xu, Chaoyuan Zeng, Hui Hu*, Yanan Gao.Theoretical study of the role of a catalytic water molecule in the hydrolysis of thionyl tetrafluoride (SOF₄). The Journal of Physical Chemistry A, 2020, 124, 5615-5620.

[37] Xinwei Liu, Huanjun Xu, Zhishuang Ma, Hongye Zhang, Cailing Wu, Zhimin Liu*. Cu-catalyzed aerobic oxygenation of 2-phenoxyacetophenones to alkyloxy acetophenones. RSC Advances, 2016, 6, 27126-27129.

[38] Yanfei Zhao, Zhenzhen Yang, Bo Yu, Hongye Zhang, Huanjun Xu, Leiduan Hao, Buxing Han, Zhimin Liu*. Task-specific ionic liquid and CO₂-cocatalysed efficient hydration of propargylic alcohols to α-hydroxy ketones. Chemical Science, 2015, 6, 2297-2301.

[39] Guipeng Ji, Zhenzhen Yang, Yanfei Zhao, Hongye Zhang, Bo Yu, Jilei Xu, Huanjun Xu, Zhimin Liu*. Synthesis of metalloporphyrin-based conjugated microporous polymer spheres directed by bipyridine-type ligands. Chemical Communications, 2015, 51, 7352-7355.

[40] Jilei Xu, Yanfei Zhao, Huanjun Xu, Hongye Zhang, Bo Yu, Leiduan Hao, Zhimin Liu*. Selective oxidation of glycerol to formic acid catalyzed by Ru(OH)₄/r-GO in the presence of FeCl₃. Applied Catalysis B: Environmental, 2014, 154, 267-273.

[41] Leiduan Hao, Yanfei Zhao, Bo Yu, Hongye Zhang, Huanjun Xu, Zhimin Liu*. Au catalyzed synthesis of benzimidazoles from 2-nitroanilines and CO₂/H₂. Green Chemistry, 2014, 16, 3039-3044.

[42] Leiduan Hao, Yanfei Zhao, Bo Yu, Hongye Zhang, Huanjun Xu, Jilei Xu, Zhimin Liu*.Polyurea-supported metal nanocatalysts: Synthesis, characterization and application in selective hydrogenation of o-chloronitrobenzene. Journal of Colloid and Interface Science, 2014, 424, 44-48.

[43] Jilei Xu, Hongye Zhang, Yanfei Zhao, Zhenzhen Yang, Bo Yu, Huanjun Xu, Zhimin Liu*. Heteropolyanion-based ionic liquids catalysed conversion of cellulose into formic acid without any additives. Green Chemistry, 2014, 16, 4931-4935.

[44] Hongye Zhang, Zhenzhen Yang,Wei Gan,Yanfei Zhao, Bo Yu,Huanjun Xu,Zhishuang Ma,Leiduan Hao,Dechao Chen,Shiding Miao, Zhimin Liu*. Hydrogen-bonding-mediated synthesis of atomically thin TiO₂ films with exposed (001) facets and applications in fast lithium insertion/extraction. Chemistry-A European Journal, 2014, 21, 14608-14613.

[45] Hongye Zhang, Yanfei Zhao, Sha Chen, Bo Yu, Jilei Xu, Huanjun Xu, Leiduan Hao, Zhimin Liu*. Ti³⁺ self-doped TiOx@anatase core-shell structure with enhanced visible light photocatalytic activity. Journal of Materials Chemistry A, 2013, 1, 6138-6144 .

[46] Xinhu Liu, Huanjun Xu, Suqin Sun, Jian Huang, Guoyu Li, Yun Zhu, Hongying Gao, Zhicheng Zhang, Jinhui Wang*. Analysis and identification of Chinese drugs by three-step infrared spectroscopy-A case study of Danshen. Analytical Methods, 2012, 4, 3344-3350.

[47] 李晓东, 康帅涛, 许环军,李国玉, 王金辉*. 糖苷化试剂-糖基三氯乙酰亚胺酯的高效制备. 沈阳药科大学学报, 2011, 28, 707-711.

[48] 康帅涛, 李晓东, 许环军,孙铁民, 黄健, 王金辉*.黄酮及其衍生物的高效合成和抗肿瘤活性. 沈阳药科大学学报, 2011, 28, 862-867.

[49] 许环军, 王学荣, 高宇, 等. 一种无金属催化体系催化氧化芳香醇类制备芳香酮类化合物的方法 (CN113861002B).

[50] 李国玉, 娄猛猛, 李晓东, 许环军, 等. 一组菊苣中的苯乙酰奎尼酸及其酯类化合物 (CN101967094B).

[51] 高艳安, 王盛林, 许环军, 等. 一种利用超临界二氧化碳制备共价有机框架材料的方法(CN110922605B).

[52] 高艳安, 田鹏, 王盛林, 许环军. 一种利用低共溶溶剂合成共价有机框架材料的方法 (CN110894299B).

王金辉, 李国玉, 许环军, 等. 一种丹参酚酸A的化学全合成方法 (CN102827002A).

四、社会服务方面

目前担任海南省化工协会理事。